A photoinduced mixed-valence state in an organic bis-triarylamine mixed-valence compound with an iridium-metal-bridge.
نویسندگان
چکیده
Upon irradiation a mixed-valence (MV) state is formed in a donor-iridium(III)-acceptor triad by a photoinduced electron transfer process. The resulting radical and intervalence charge transfer (IV-CT) absorptions cover a wide spectral range (3200-400 nm). These results were supported by spectroelectrochemistry, fs-time resolved pump-probe spectroscopy and assisted by TD-DFT calculations.
منابع مشابه
Mulliken-Hush analysis of a bis(triarylamine) mixed-valence system with a N...N distance of 28.7 A.
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عنوان ژورنال:
- Chemical communications
دوره 50 77 شماره
صفحات -
تاریخ انتشار 2014